Akiyama Group Publication List

秋山研究室の研究成果 The Akiyama Group Publication List

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152			gamma-Silylboronates in the chiral Bronsted acid-catalysed allylboration of aldehydes
152			Barrio, P.; Rodriguez, E.; Saito, K.; Fustero, S.; Akiyam, T. Chem. Commun. 2015, 51, Advance Article, DOI: 10.1039/C4CC08598A
151			Synthesis of 3-Aryl-1-trifluoromethyltetrahydroisoquinolines by Bronsted Acid Catalyzed C(sp³)-H Bond Functionalization
151			Mori, K.; Umehara, N.; Akiyama, T. Adv. Synth. Catal. 2015, 357, VIP, Early View, DOI:10.1002/adsc.201400775.
150			Enantioselective Synthesis of Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy
150			Mori, K.; Kobayashi, M.; Itakura, T.; Akiyama, T. Adv. Synth. Catal. 2015, 357, 35-40.
149			Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable, Hydrogen Donor
149			Saito, K.; Miyashita, H.; Akiyama, T. Org. Lett. 2014, 16, 5312-5315.
148			Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimine Derivatives; Remarkable Difference in Enantioselectivity depending on Hydrogen donors
148			Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Chem. Eur. J. 2014, 20, 7616-7620.
147			Phosphoric Acid Bridged Cobalt Bis(dicarbollide) Ion as a Highly Efficient Catalyst for the Organocatalytic Hydrogenation of Ketimines
147			Akiyama, T.; Saito, K.; Janczak, S.: Lesnikowski, Z. Synlett 2014, 25, 795-798.
146			Stereoselective Construction of All Carbon Quaternary Center by Chiral Phosphoric Acid: Highly Enantioselective Friedel-Crafts Reaction of Indoles with beta,beta-Disubstituted Nitoroalkenes
146			Mori, K.; Wakazawa, M.; Akiyama, T. Chem. Sci. 2014, 5, 1799-1803.
145			Double C(sp³)-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles
145			Mori, K.; Kurihara, K.; Yabe, S.; Yamanaka, M.; Akiyama, T. J. Am. Chem. Soc. 2014, 136, 3744-3747.
144			Expeditious Synthesis of 1-Aminoindane Derivatives Achieved by [1,4]-Hydride Shift Mediated C(sp³)-H Bond Functionalization
144			Mori, K.; Kurihara, K.; Akiyama, T. Chem. Commun. 2014, 50, 3729-3731.
143			Enantioselective Fluorination of b-Ketoesters Catalyzed by Chiral Sodium Phosphate: Remarkable Enhancement of Reactivity by Simultaneous Utilization of Metal Enolate and Metal Phosphate
143			Mori, K.; Miyake, A.; Akiyama, T. Chem. Lett. 2014, 43 , 137-139.
142			Chiral Copper(II) Phosphate Catalyzed Enantioselective Synthesis of Isochromene Derivatives by Sequential Intramolecular Cyclization and Asymmetric Transfer Hydrogenation of o-Alkynylacetophenones
142			Saito, K.; Kajiwara, Y.; Akiyama, T. Angew. Chem. Int. Ed. 2013, 52, 13284-13288.
141			Enantioselective Transfer Hydrogenation of Difluoromethyl Ketimines Using Benzothiazoline as a Hydrogen Donor in Combination with Chiral Phosphoric Acid
141			Sakamoto, T.; Horiguchi, K.; Saito, K.; Mori, K.; Akiyama, T. Asian J. Org. Chem. 2013, 2 , 943-946.
140			Prediction of Suitable Catalyst by ¹H NMR: Asymmetric Synthesis of Multisubstituted Biaryls by Chiral Phosphoric Acid Catalyzed Asymmetric Bromination
140			Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Chem. Sci. 2013, 4, 4235-4239.
139			Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines
139			Saito, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T, J. Am. Chem. Soc. 2013, 135, 11740-11743.
138			Hydrodefluorinations of Trifluorotoluenes by LiAlH₄ and TiCl₄
138			Akiyama, T.; Atobe, K.; Shibata, M.; Mori, K. J. Fluorine Chem. 2013, 152, 81-83.
137			Molecular Iodine Catalyzed Transfer Hydrogenation: Reduction of Aldimines, Ketimines, and a-Imino esters
137			Bachu, P.; Zhu, C.; Akiyama, T. Tetrahedron Lett. 2013, 54, 3977-3981.
136			Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence
136			Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; Akiyama, T. J. Am. Chem. Soc. 2013, 135 , 3964-3970.
135			Kinetic Resolution in Chiral Bronsted Acid Catalyzed Aldol Reaction: Enantioselective Robinson-type Annulation Reaction
135			Yamanaka, M.; Hoshino, M.; Katoh, T.; Mori, K.; Akiyama, T. Eur. J. Org. Chem. 2012, 4508-4514.
134			Phopshoric Acid Catalyzed Enantioselective Transfer Deruteration of Ketimines by Use of Benzothiazoline as a Deuterium Donor: Synthesis of Optically Active Deuterated Amines
134			Sakamoto, T.; Mori, K.; Akiyama, T. Org. Lett. 2012, 14, 3312-3315.
133			Enantioselective Organocatalytic Reductive Amination of Aliphatic Ketones by Benzothiazoline as Hydrogen Donor
133			Saito, K.; Akiyama, T. Chem. Commun. 2012, 48, 4573-4575.
132			Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp³)-H Bond Functionalization and Its Application to Formal Synthesis of (+-)-Tetrahydropalmatine
132			Mori, K.; Kawasaki, T.; Akiyama, T. Org. Lett. 2012, 14, 1436-1439.
131			Carboxyl-Tailed Benzothiazoline: A Readily Removable Hydrogen Donor for the Transfer Hydrogenation of Imines
131			Zhu, C.; Akiyama, T. Tetrahedron Lett. 2012, 53, 416-418.
130			Rapid Access to 3-Aryltetraline Skeleton via C(sp³)-H Bond Functionalization: Investigation on the Substituent Effect of Aromatic Ring Adjacent to C-H Bond in Hydride Shift/Cyclization Sequence
130			Mori, K.; Sueoka, S.; Akiyama, T. Chem. Lett. 2011, 40 , 1386-1388.
129			Development of Chiral Bronsted Acid and its Application to Asymmetric Synthesis
129			T. Akiyama, J. Synth. Org. Chem. Jpn., 2011, 69, 913-925.
128			Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation: A Facile Synthetic Access to Highly Optically Active Trifluoromehylated Amines
128			Henseler, A.; Kato, M.; Mori, K.; Akiyama, T. Angew. Chem. Int. Ed. 2011, 50, 8180-8183.
127			Bronsted Acid Catalyzed Reductive Amination with Benzothiazoline as a Hyighly Efficient Hydrogen Donor
127			Zhu, C.; Akiyama, T. Synlett (Cluster, Bronsted Acid, invited), 2011, 1251-1254.
126			Selective Activation of Enantiotopic C(sp³)-Hydrogen by Means of Chiral Phosphoric Acid: Asymmetric Synthesis of Tetrahydroquinoline Derivatives
126			Mori, K.; Ehara, K.; Kurihara, K.; Akiyama, T. J. Am. Chem. Soc. 2011, 133, 6166-6169.
125			Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of b-Amino-a,a-difluoro Carbonyl Compounds
125			Kashikura, W.; Mori, K.; Akiyama, T. Org. Lett. 2011, 13, 1860-1863.
124			Expeditious Construction of a Carbobicyclic Skeleton via a sp3-C-H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process
124			Mori, K.; Sueoka, S.; Akiyama, T. J. Am. Chem. Soc. 2011, 133, 2424-2426.
123			Chiral Bronsted Acid-Catalyzed Asymmetric Friedel-Crafts Alkylation of Indoles with a,b-Unsaturated Ketones: Short Access to Optically Active 2- and 3-Substituted Indole Derivatives
123			Sakamoto, T.; Itoh, J.; Mori, K.; Akiyama, T. Org. Biomol. Chem. 2010, 8, 5448-5454.
122			A One-pot Tandem Approach of Synthesis of Benzothiazoles from Benzyl Halides
122			Zhu, C.; Akiyama, T. Synlett 2010, 2457-2460.
121			Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of a-Imino Esters
121			Zhu, C.; Akiyama, T. Adv. Synth. Catal. 2010, 352, 1846-1850.
120			Niobium-catalyzed Activation of CF₃ Group on Alkene: Synthesis of Substituted Indenes
120			Fuchibe, K.; Atobe, K.; Fujita, Y.; Mori, K.; Akiyama, T. Chem. Lett. 2010, 39, 867-869.
119			Synthesis and Properties of Phosphoroselenoic Acids, and their Salts Bearing Binaphthyl Groups
119			Murai, T.; Monzaki, M.; Katoh, T.; Suzuki, T.; Akiyama, T. Phosphorus, Sulfur, Silicon Relat. Elem. 2010, 185, 964-973.
118			Enantioselective Friedel-Crafts Alkylation Reaction of Indoles with a,b-Unsaturated Acyl Phosphonates Catalyzed by Chiral Phosphoric Acid
118			Bachu, P.; Akiyama, T. Chem. Commun. 2010, 46, 4112-4114.
117			Expeditous Synthesis of Benzopyrans via Lewis Acid-Catalyzed C-H Functionalization: Remarkable Enhancement of Reactivity by an Ortho Substituent
117			Mori, K.; Kawasaki, T.; Sueoka, S.; Akiyama, T. Org. Lett. 2010, 12, 1732-1735.
116			Enantioselective Friedel-Crafts Alkylation of Indoles, Pyrroles, and Furans with Trifluoropyruvates catalyzed by Chiral Phosphoric Acid
116			Kashikura, W.; Itoh, J.; Mori, K.; Akiyama, T. Chem. Asian J. 2010, 5, 470-472.
115			Chiral Phosphoric Acid Catalyzed Desymmetrization of meso-1,3-Diones: Asymmetric Synthesis of Chiral Cyclohexenones
115			Mori, K.; Katoh, T.; Suzuki, T.; Noji, T.; Yamanaka, M.; Akiyama, T. Angew. Chem. Int. Ed. 2009, 48 , 9652-9654.
114			Expedient Synthesis of N-Fused Indoles: C-F Activation and C-H Insertion Approach
114			Fuchibe, K.; Kaneko, T.; Mori, K.; Akiyama, T. Angew. Chem. Int. Ed. (VIP article) 2009, 48, 8070-7073.
113			Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of Ketimines
113			Zhu, C.; Akiyama, T. Org. Lett. 2009, 11 , 4180-4183.
112			Bronsted Acid-catalyzed Nazarov Cyclization of Pyrrole Derivatives by Microwave Acceleration
112			Bachu, P.; Akiyama, T. Bioorg. Med. Chem. Lett. (Tetrahedron Young Investigator Award Issue for Carlos F. Barbas, invited), 2009, 19 , 3764-3766
111			Chiral Bronsted Acid Catalzyed Hydrophosponylation of Aldimines: DFT Study on the Effect of Substituenst on the Phosphoric Acid
111			Akiyama, T.; Morita, H.; Bachu, P.; Mori, K.; Yamanaka, M.; Hirata, T. Tetrahedron (Tetrahdedon Young Investigator Award Issue for Michael J. Krische, invited), 2009, 65, 4950-4956.
110			Enantioselective Mannich-type Reaction Catalyzed by a Chiral Phosphoric Acid Bearing (S)-Biphenol Backbone
110			Akiyama, T.; Katoh, T.; Mori, K.; Kanno, K. Synlett (Cluster: Bifunctional Catalyst, invited), 2009, 1664-1666.
109			Dual Functionalization of Allene: Facile Construction of Heteropolycycles Catalyzed by Bronsted Acid
109			Mori, K.; Sueoka, S.; Akiyama, T. Chem. Lett. 2009, 38, 628-629.
108			Concise Construction of Quinazolines via Bronsted Acid Induced C-H Activation: Further Extentions of the "tert-Amino Effect",
108			Mori, K.; Ohshima, Y.; Ehara, K.; Akiyama, T. Chem. Lett. 2009, 38, 524-525.
107			Enantioselective Aza Darzens Reaction Catalyzed by a Chiral Phosphoric Acid
107			Akiyama, T.; Suzuki, T.; Mori, K. Org. Lett. 2009, 11, 2445-2447. (Highlighted in Synfacts)
106			Enantioselective Robinson-Type Annulation Reaction Catalyzed by Chiral Phosphoric Acids
106			Akiyama, T; Katoh, T.; Mori, K. Angew. Chem. Int. Ed. 2009, 48, 4226-4228. (Highlighted in Synfacts)
105			Catalytic Activation of Carbon-fluorine Bonds by Low-valent Niobium Species
105			Fuchibe, K.; Akiyama, T. J. Synth. Org. Chem. Jpn. 2009, 67, 208-218.
104			Mechanistic Study on the Base-Promoted Synthesis of Alkenylsilanols from Allylsilanes
104			Imazeki, S.; Sugawara, H.; Sano, A.; Akiyama, T. Bull. Chem. Soc. Jpn. 2008, 81, 623-629.
103			Chiral Phosphoric Acid-Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with Nitroalkenes-Cooperative Effect of MS 3A
103			Itoh, J.; Fuchibe, K.; Akiyama, T. Angew. Chem. Int. Ed. 2008, 48 , 4016-4018. (Highlighted in Synfacts)
102			Preparation of b-Amino Esters by Chiral Bronsted Acid-Catalyzed Mannich-type Reaction
102			Itoh, J.; Fuchibe, K.; Akiyama, T. Synthesis (PSP article, invited), 2008, 1319-1322.
101			Vinylogous Mannich-type Reaction Catalyzed by an Iodine-Substituted Chiral Phosphoric Acid
101			Akiyama, T. Honma, Y.; Itoh, J.; Fuchibe, K. Adv. Synth. Catal. 2008, 350, 399-402. (Highlighted in Synfacts)
100			C－C Coupling Reactions of Superstrong CF3 Groups with sp2 Carbon－hydrogen Bonds: Reactivity and Synthetic Utility of Zero-valent Niobium Catalyst
100			Fuchibe, K.; Mitomi, K.; Suzuki, R. Akiyama, T. Chem. Asian J. (Special Issue in celebration of the 80th Birthday of Professor Teruaki Mukaiyama, Invited), 2008, 3, 261-271.
99			Stronger Bronsted Acid
99			Akiyama, T. Chem. Rev. (Thematic Issue on Organocatalysis, Invited), 2007, 107, 5744-5758.
98			Hydrodefluorinations by Low-valent Niobium Catalyst
98			Fuchibe, K.; Ohshima, Y.; Mitomi, K.; Akiyama, T. J. Fluorine Chem. (Special Issue dedicated to Prof. Kenji Uneyama, Invited), 2007, 128, 1158-1167.
97			Chiral Bronsted Acid-Catalyzed Enantioselective Mannich-type Reaction
97			Yamanaka, M.; Itoh, J.; Fuchibe, K.; Akiyama, T. J. Am. Chem. Soc. 2007, 129, 6756-6764.
96			Carbocyclization Reaction of Malonate Derivatives with Allylsilane Moiety Mediated by AlCl₃-n-Bu₃N
96			Imazeki, S.; Kinoshita, R.; Akiyama, T. Bull. Chem. Soc. Jpn. 2007, 80, 972-978.
95			Low-Valent Niobium-Catalyzed Reduction of a,a,a-Trifluorotoluenes
95			Fuchibe, K.; Ohshima, Y.; Mitomi, K.; Akiyama, T. Org. Lett. 2007, 9, 1497-1499.
94			Synthesis of Nitrogen-containing Compounds Using Chromium Fischer Carbene Complexes
94			Kagoshima, H.; Fuchibe, K.; Akiyama, T. Chem. Rec. 2007, 7, 104-114.
93			Low-valent Niobium-mediated Synthesis of Indenes: Intramolecular Coupling Reactions of CF3 Group with Alkene C-H Bond
			Fuchibe, K.; Mitomi, K.; Akiyama, T. Chem. Lett. 2007, 36, 88-89.

92			Mannich-type Reaction in Water in the Presence of a Surfactant
92			Itoh, J.; Fuchibe, K.; Akiyama, T. Synthesis (Special Topic, Mannich Reactions: Invited) 2006, 4075-4080.
91			One-Pot Synthesis of Chiral Dehydroproline Esters: [3+2]-Type Cycloaddition Reaction of Allenylstannane and a-Imino Ester
91			Fuchibe, K.; Hatemata, R.; Akiyama, T. Tetrahedron (Tetrahedron Young Investigator Award Issue (David MacMillan), Invited) 2006, 62, 10304-10310 . (Highlighted in Synfacts)
90			Chiral Bronsted Acid-Catalyzed Inverse Electron Electron-Demand Aza Diels-Alder Reaction
90			Akiyama, T.; Morita, H.; Fuchibe, K. J. Am. Chem. Soc. 2006, 128, 13070-13071. (Highlighted in Synfacts)
89			Chiral Bronsted Acid Catalyzed Enantioselective Aza Diels-Alder Reaction of Brassard's Diene with Imines
89			Itoh, J.; Fuchibe, K.; Akiyama,T. Angew. Chem. Int. Ed. 2006, 45, 4796-4798. (Highlighted in Synfacts)
88			Recent Progress in the Chiral Bronsted Acid Catalysis
88			Akiyama, T.; Itoh, J.; Fuchibe, K. Adv. Synth. Catal. 2006, 348, 999-1010.
87			Synthesis of Pyrroles: Reaction of Chromiun N-Alkylaminocarbene Complexes with a,b-Unsaturated Aldehydes
87			Fuchibe, K.; Ono, D.; Akiyama, T. Chem. Commun. 2006, 2271-2273.
86			Low Valent Niobium-mediated Double Activation of C-F/C-H Bonds: Fluorene Synthesis from o-Arylated a,a,a-Trifluorotoluene Derivatives
86			Fuchibe, K.; Akiyama, T. J. Am. Chem. Soc. 128, 1434-1435 (2006). (Highlighted in Synfacts)
85			Stereoselective Synthesis of Tetrahydrofuran by Diastereoselective [3+2] Cycloaddition Reaction of Chiral Allylsilane with a-Keto Ester
85			Akiyama, T.; Funaki, S.; Fuchibe, K. Heterocycles (Prof. Trost's Special Issue) 67, 369-374 (2006).
84			Enantioselective Aza Diels-Alder Reaction Catalyzed by a Chiral Bronsted Acid: Effect of the Additive on the Enantioselectivity
84			Akiyama, T.; Tamura, Y.; Itoh, J.; Morita, H.; Fuchibe, K. Synlett (Cluster: Bronsted Acid: Invited) 2006, 141-143. (Highlighted in Synfacts)
83			Chiral Bronsted Acid-catalyzed Addition and Cycloaddition Reaction with Imine: From Aqueous Reaction to Enantioselective Reactions
83			Akiyama, T.; Itoh, J.; Fuchibe, K. J. Synth. Org. Chem. Jpn. 63, 1062-1068 (2005).
82			Enantioselective Three-Component Synthesis of 4-Arylated Dehydroprolines: [3+2] Annulation of Allenylstannane and a-Imino Ester
82			Fuchibe, K.; Hatemata, R.; Akiyama, T.Tetrahedron Lett. 46, 8563-8566 (2005).
81			Enantioselective Mannich-type Reaction Catalyzed by a Bronsted Acid Derived from TADDOL
81			Akiyama, T.; Saitoh, Y.; Morita, H.; Fuchibe, K. Adv. Synth. Catal. (Special Issue: Catalytic C-C Bond Formation: Invited) 347, 1523-1526 (2005). (Highlighted in Synfacts)
80			Montmorillonite K10 Catalyzed Nucleophilic Addition Reaction to Aldimines in Water
80			Akiyama, T.; Matsuda, K.; Fuchibe, K. Synthesis (Special Topic: Aqueous Chemistry: Invited) 2005, 2606-2608.
79			Chiral Bronsted Acid-catalyzed Enantioselective Hydrophosphonylation of Imines: Asymmetric Synthesis of a-Amino Phosphonates
79			Akiyama, T.; Morita, H.; Itoh, J.; Fuchibe, K. Org. Lett. 7, 2583-2585 (2005). (Highlighted in Synfacts)
78			Mannich-type Reaction Promoted by an Ionic Liquid
78			Akiyama, T.; Suzuki, A.; Fuchibe, K. Synlett 2005, 1024-1026.
77			[3+2] Cycloaddition Reactions of Cyclopropylmethylsilanes and a-Keto Aldehydes: Trans- and Cis-Selective Formation of 2-Silylmethyltetrahydrofurans
77			Fuchibe, K.; Aoki, Y.; Akiyama, T. Chem. Lett. 33, 538-539 (2005).
76			Cu(I)-Catalyzed Enantioselective [3+2] Cycloaddition Reaction of 1-Alkylallenylsilanewith a-Imino Ester: Chiral Synthesis of Pyrroline Derivatives
76			Daidouji, K.; Fuchibe, K.; Akiyama, T.Org. Lett. 7, 1051-1053 (2005). (Highlighted in Synfacts)
75			HCl-catalyzed Stereoselective Mannich Reaction in H₂O-SDS System
75			Akiyama, T.; Matsuda, K.; Fuchibe, K. Synlett 2005, 322-324.
74			Synthesis of Aryl-substituted Quinoline Derivatives via Bronsted Acid-Catalyzed [4+2] Aza Diels-Alder Reaction
74			T. Akiyama, S. Nakashima, K. Yokota, and K. Fuchibe, Chem. Lett. 33, 922-923 (2004).
73			Facile Method for the Preparation of Triarylsulfonium Bromides Using Grignard Reagents and Chlorotrimethylsilane as an Activator
73			Imazeki, S.; Sumino, M.; Fukasawa, K.; Ishihara, M.; Akiyama, T. Synthesis 2004, 1648-1654.
72			Niobium-catalyzed Reduction of Monofluoroarenes with LiAlH^₄
72			Fuchibe, K.; Akiyama, T. Synlett 2004, 1282-1284.
71			Enantioselective Mannich-type Reaction Catalyzed by a Chiral Bronsted Acid
71			Akiyama, T.; Itoh, J.; Yokota, K.; Fuchibe, K. Angew. Chem. Int. Ed. 43, 1566-1568 (2004).
70			A Novel Approach to 2-Substituted Quinolines: Electrocyclization of Alkynyl Imines via Vinylidene Complexes
70			Sangu, K.; Fuchibe, K.; Akiyama, T. Org. Lett. 6, 353-355 (2004).
69			Cu(I)-catalyzed Enantioselective [2+2] Cycloaddition of 1-Methoxyallenylsilane with a-Imino Ester: Chiral Synthesis of a,b-Unsaturated Acylsilanes
69			T. Akiyama, K.Daidouji, and K. Fuchibe, Org. Lett., 5, 3691-3693 (2003).
68			Bronsted Acid-Mediated Synthesis of a-Amino Phosphonates under Solvent-Free Conditions
68			T. Akiyama, M. Sanada, and K. Fuchibe, Synlett, 2003, 1463-1464.
67			Synthesis of A Novel Crown Ether Derived from chiro-Inositol and Its Catalytic Activity On The Asymmetric Michael Addition
67			T. Akiyama, M. Hara, K.Fuchibe, S. Sakamoto, and K. Yamaguchi, Chem. Commun., 2003, 1734-1735.
66			Stereoselective Synthesis of CF₃-Substituted Aziridines by Lewis Acid-Mediated Aziridination of Aldimines with Diazoacetates
66			T. Akiyama, S. Ogi, and K. Fuchibe, Tetrahedron Lett., 44, 4011-4013 (2003).
65			Montmorillonite K10-Catalyzed Aza Diels-Alder Reaction of Danishefsky's Diene with Aldimines, Generated in situ from Aliphatic Aldehydes and Amine, in Aqueous Media
65			T. Akiyama, K. Matsuda, and K. Fuchibe, Synlett, 2002, 1898-1900.
64			Novel Thermal Reaction of Fischer Carbene Complexes with Imines: Synthesis of b-Methoxy Allylic Amine Derivatives
64			K. Sangu, H. Kagoshima, K. Fuchibe, and T. Akiyama, Org. Lett., 4, 3967-3969 (2002).
63			Mannich-type Reaction Catalyzed by HBF₄ in Water: Effect of the Loading of Surfactant
63			T. Akiyama, J. Itoh, and K. Fuchibe, Synlett, 2002, 1269-1272.
62			Bronsted Acid Catalyzed Mannich-Type Reactions in Aqueous Media
62			T. Akiyama, J. Takaya, and H. Kagoshima, Adv. Synth. Catal. (Water Issue: Invited), 343, 338-347 (2002).
61			Tin(II) Chloride Mediated Allylation of Aldimines Generated in situ with Allylstannane in Water,
61			T. Akiyama and Y. Onuma, J. Chem. Soc., Perkin Trans 1, 2002, 1157-1158.
60			Catalytic, Enantioselective Propargyl- and Allenylation Reactions of a-Imino Esters
60			H. Kagoshima, T. Uzawa, and T. Akiyama, Chem. Lett., 2002, 298-299.
59			The Asymmetric [3+2] Cycloaddition Reaction of Chiral Alkenyl Fischer Carbene Complexes with Imines: Synthesis of Optically Pure 2,5-Disubstituted-3-Pyrrolidinones
59			H. Kagoshima, T. Okamura, and T. Akiyama, J. Am. Chem. Soc., 123, 7182-7183 (2001).
58			Highly Stereo-Divergent Mannich-type Reaction Catalyzed by Bronsted Acid in Aqueous Media,
58			T. Akiyama, J. Takaya, and H. Kagoshima, Tetrahedron Lett., 42, 4025-4028 (2001).
57			Lewis Acid-Mediated [3+2] Cycloaddition of Allyltriisopropylsilane to N-Sulfonyl Aldimines
57			T. Akiyama, M. Sugano, and H. Kagoshima, Tetrahedron Lett., 42, 3889-3992 (2001).
56			Novel [3+2] Cycloaddition Reaction of Alkenyl Fischer Carbene Complexes with Imines Leading to 3-Pyrroline Derivatives
56			H. Kagoshima and T. Akiyama, J. Am. Chem Soc., 122, 11741-11742 (2000) .
55			Mannich-type Reaction with Trifluoromethylated N,O-Hemiacetal: Facile Preparation of b-Amino-b-Trifluoromethyl Carbonyl Compounds
55			J. Takaya, H. Kagoshima, and T. Akiyama, Org. Lett., 2, 1577-1579 (2000).
54			Development of Novel Synthetic Reactions Using Allylsilane
54			T. Akiyama, J. Synth. Org. Chem. Jpn., 58, 285-292 (2000).
53			Lewis Acid Promoted [4+2] Annulation of Allylsilane and Allylgermane with Aldimine; Preparation of Tetrahydroquinolines
53			T. Akiyama, M. Suzuki, and H. Kagoshima, Heterocycles, 52, 529-532 (2000).
52			Chemoselective Allylation of Aldimine with Allyltriethylgermane By the Combined Use of BF₃OEt₂ and CH₃CO₂H
52			T. Akiyama, J. Iwai, Y. Onuma, and H. Kagoshima, J. Chem. Soc., Chem. Commun., 1999, 2191-2192.
51			Bronsted Acid-Catalyzed Aza Diels-Alder Reaction of Danishefsky's Diene with Aldimine Generated in situ from Aldehyde and Amine in Aqueous Media
51			T. Akiyama, J. Takaya, and H. Kagoshima, Tetrahedron Lett., 40, 7831-7834 (1999).
50			Chemoselective Activation of Aldimine in Preference to Aldehyde by the Combination of BF3OEt2 and Water: Novel Catalyst for the Mannich-type Reaction
50			T. Akiyama, J. Takaya, and H. Kagoshima, Chem. Lett., 1999, 947-948.
49			One-pot Mannich-Type Reaction In Water: HBF₄ Catalyzed Condensation of Aldehydes, Amines, and Silyl Enolates for the Synthesis of b-Amino Carbonyl Compounds
49			T. Akiyama, J. Takaya, and H. Kagoshima, Synlett, 1999, 1426-1428.
48			HBF₄ Catalyzed Mannich-Type Reaction In Aqueous Media
48			T. Akiyama, J. Takaya, and H. Kagoshima, Synlett, 1999, 1045-1046.
47			Scandium Trifluoromethanesulfonate-Catalyzed Chemoselective Allylation Reactions of Carbonyl Compounds with Tetraallylgermane in Aqueous Media
47			T. Akiyama, J. Iwai, and M. Sugano, Tetrahedron, 55, 7499-7508 (1999).
46			Chiral Syntheses of 2,3,5-Trisubstituted Pyrrolidines by Silicon-Directed Cyclization of Allylsilanes Bearing a Sulfonamide Moiety
46			T. Akiyama, Y. Ishida, and H. Kagoshima, Tetrahedron Lett., 40, 4219-4222 (1999).
45			Lewis Acid Mediated Domino Allylation of Diallylsilane to a,b-Unsaturated Ketones,
45			T. Akiyama, K. Asayama, and S. Fujiyoshi, J. Chem. Soc., Perkin Trans 1, 1998, 3655-3656.
44			Stereoselective Synthesis of 2,3,5-Substituted Tetrahydrofurans by Silicon-Directed Cyclization of Allylsilanes Bearing a Hydroxy Moiety
44			T. Akiyama and Y. Ishida, Synlett, 1998, 1150-1152.
43			Stereoselective Synthesis of Cyclopentanols by Lewis Acid-Mediated [3+2] Annulation of Allyldiisopropylphenylsilane with a,b-Unsaturated Diesters,
43			T. Akiyama, and M. Yamanaka, Tetrahedron Lett., 39, 7885-7888 (1998).
42			Allyldiisopropylphenylsilane As a Synthetic Equivalent of 2-Hydroxy-1,3-DipoleStereoselective Synthesis of Cyclopentanols
42			T. Akiyama, E. Hoshi, and S. Fujiyoshi, J. Chem. Soc., Perkin Trans 1, 1998, 2121-2122.
41			Three-Component Synthesis of Homoallylamines by Scandium(III) Triflate-Mediated Allylation with Allylgermane: A Highly Imine Selective Allylation Reaction
41			T. Akiyama and J. Iwai, Synlett, 1998, 273-274.
40			Lewis Acid Mediated [3+2] Cycloaddition of Allylgermane: Stereoselective Synthesis of Germyl Substituted Tetrahydrofurans
40			T. Akiyama and M. Suzuki, J. Chem. Soc., Chem. Commun., 1997, 2357-2358.
39			Base Promoted Preparation of Alkenylsilanols from Allylsilanes
39			T. Akiyama and S. Imazeki, Chem. Lett., 1997, 1077-1078.
38			Novel Lewis Acid Promoted Reactions of Allylsilane Bearing Bulky Silyl Substituents and Aldehydes
38			T. Akiyama, M. Nakano, J. Kanatani, and S. Ozaki, Chem. Lett., 1997, 385-386.
37			The Scandium Trifluoromethanesulfonate-Catalyzed Chemoselective Allylation Reactions of Carbonyl Compounds with Tetraallylgermane in Aqueous Media
37			T. Akiyama and J. Iwai, Tetrahedron Lett., 38, 853-856 (1997).
36			Preparation of Oxetanes by Zirconium(IV) Chloride Promoted Cycloaddition of Allylsilane to Aldehydes,
36			T. Akiyama and M. Yamanaka, Synlett, 1996, 1095-1096.
35			L-Quebrachitol as a New Chiral Building Block
35			T. Akiyama, J. Synth. Org. Chem. Jpn., 1996, 54, 84-93.
34			Stereodivergent Diels-Alder Reactions Employing Cyclitols as Chiral Auxiliaries,
34			T. Akiyama, N. Horiguchi, T. Ida, and S. Ozaki, Chem. Lett., 1995, 975-976.
33			Stereoselective Construction of Oxetane by Titanium(IV) Chloride Promoted [2+2] Cycloaddition of Allylsilane to a-Keto Esters
33			T. Akiyama and M. Kirino, Chem. Lett., 1995, 723-724.
32			Asymmetric Synthesis of Tetrahydrofurans by Diastereoselective [3+2] Cycloaddition of Allylsilanes with a-Keto Esters Bearing an Optically Active Cyclitol as a Chiral Auxiliary
32			T. Akiyama, T. Yasusa, K. Ishikawa, and S. Ozaki, Tetrahedron Lett., 35, 8401-8404 (1994).
31			Mild Deprotection of Methyl, Benzyl, Methoxymethyl, Methylthiomethyl, Methoxyethoxymethyl, and b-(Trimethylsilyl)ethoxymethyl Esters with AlCl₃-N,N-Dimethylaniline
31			T. Akiyama, H. Hirofuji, A. Hirose, and S. Ozaki, Synth. Commun., 24, 2179-2185 (1994).
30			Asymmetric Synthesis of Functionalized Tertiary Alcohols by Diastereoselective Aldol Reaction of Silyl Enol Ether and Ketene Silyl Acetal with a-Keto Esters Bearing an Optically Active Cyclitol as a Chiral Auxiliary
30			T. Akiyama, K. Ishikawa, and S. Ozaki, Synlett , 1994, 275-276.
29			Stereoselective Construction of Tetrahydrofuran by Tin (IV) Chloride Promoted [3+2] Cycloaddition of Allylsilane to a-Keto Ester
29			T. Akiyama, K. Ishikawa, and S. Ozaki, Chem. Lett., 1994, 627-630.
28			Stereodivergent Synthesis of Optically Active a-Hydroxy Acids via Diastereoselective Reduction of a-Keto Esters Derived from L-Quebrachitol
28			T. Akiyama, H. Nishimoto, T. Kuwata, and S. Ozaki, Bull. Chem. Soc. Jpn., 67, 180-188 (1994).
27			Syntheses of (-)-Conduritol F, (+)-Conduritol B, and Cyclophellitol from L-Quebrachitol
			T. Akiyama, H. Shima, M. Ohnari, T. Okazaki, and S. Ozaki, Bull. Chem. Soc. Jpn., 66, 3760-3767 (1993).
26			Enzymatic Resolution of Racemic 1,2:4,5-Di-O-cyclohexylidene and 1,2:3,4-Di-O-cyclohexylidene-myo-Inositol,
			L. Ling, X. Li, Y. Watanabe, T. Akiyama, and S. Ozaki, Bioorg. Med. Chem. 1, 155-159 (1993).
25			The Preparation of Optically Active ?2-Isoxazolines via Addition of Nitrile Oxides to Chiral Acryloyl Esters Bearing Cyclitols as Auxiliaries
			T. Akiyama, K. Okada, and S. Ozaki, Tetrahedron Lett., 33, 5763-5766 (1992).
24			AlCl3-N,N-Dimethylaniline: A Novel Benzyl and Allyl Ether Cleavage Reagent
			T. Akiyama, H. Hirofuji, and S. Ozaki, Bull. Chem. Soc. Jpn., 65, 1932-1938 (1992).
23			Trimethylsilyl Chloride-Tin(II) Chloride-Anisole: A Novel Selective p-Methoxybenzyl Ether Cleavage Reagent,
			T. Akiyama, H. Shima, and S. Ozaki, Synlett, 1992, 415-416.
22			A New Efficient Method for Resolution of myo-Inositol Derivatives by Enzyme Catalyzed Regio- and Enantio-selective Esterification in Organic Solvent
			L. Ling, Y. Watanabe, T. Akiyama, and S. Ozaki, Tetrahedron Lett., 33, 1911-1914 (1992).
21			Diastereoselective Addition of Organometallics to a-Keto Esters Bearing chiro-Inositol Derivatives as Chiral Auxiliaries,
			T. Akiyama, H. Nishimoto, K. Ishikawa, and S. Ozaki, Chem. Lett., 1992, 447-450.
20			Chiral Synthesis of D-myo-Inositol 1-Phosphate Starting from L-Quebrachitol
			T. Akiyama, N. Takechi, S. Ozaki, and K. Shiota, Bull. Chem. Soc. Jpn., 65, 366-372 (1992).
19			Total Synthesis of Cyclophellitol from L-Quebrachitol
			T. Akiyama, M. Ohnari, H. Shima, and S. Ozaki, Synlett, 1991, 831-832.
18			A Concise Synthesis of (-)-Conduritol F from L-Quebrachitol via AlCl3-n-Bu4NI Mediated Demethylation
			T. Akiyama, H. Shima, and S. Ozaki, Tetrahedron Lett., 32, 5593-5596 (1991).
17			A Synthesis of 5'-O-Acryloyl-5-Fluorouridine by Use of p-Methoxybenzyl Group as an N3-Imide Protecting Group of 5-Fluorouridine
			T. Akiyama, M. Kumegawa, Y. Takesue, H. Nishimoto, and S. Ozaki, Bull. Chem. Soc. Jpn., 64, 2266-2269 (1991).
16			Diastereoselective Reduction of a-Keto Esters Bearing chiroInositol deteremined based ones
			T. Akiyama, H. Nishimoto, and S. Ozaki, Tetrahedron Lett., 32, 1335-1338 (1991).
15			AlCl3-N,N-Dimethylaniline: A New Benzyl and Allyl Ether Cleavage Reagent
			T. Akiyama, H. Hirofuji, and S. Ozaki, Tetrahedron Lett., 32, 1321-1324 (1991).
14			5-Fluorouracil Derivatives. XX. Synthesis and Antitumor Activity of 5'-O-Unsaturated Acyl 5-Fluorouridines
			S. Ozaki, T. Akiyama, T. Morita, M. Kumegawa, T. Nagase, N. Uehara, and A. Hoshi, Chem. Pharm. Bull., 38, 3164-3166 (1990).
13			The Selective Protection of Uridine with a p-Methoxybenzyl Chloride: A Synthesis of 2'-O -Methyluridine
			T. Akiyama, H. Nishimoto, and S. Ozaki, Bull. Chem. Soc. Jpn., 63, 3356-3357 (1990).
12			Anchimerically Assisted Demethylation of Methyl Ethers in Inositol Derivatives with an AlCl3-NaI System
			T. Akiyama, N. Takechi, H. Shima, and S. Ozaki, Chem. Lett., 1990, 1881-1884.
11			Preparation of Antitumor Active Vinyl Polymers Containing 5-Fluorouracil as a Component,
			S. Ozaki, J. Ohnishi, T. Akiyama, T. Nagase, N. Uehara, and A. Hoshi, Polym. J., 22, 689-695 (1990).
10			A Chiral Synthesis of D-myo-Inositol 1-Phosphate Starting from L-Quebrachitol
			T. Akiyama, N. Takechi, and S. Ozaki, Tetrahedron Lett., 31, 1433-1434 (1990).
9			p-Methoxybenzyl as a New N3-Imide Protecting Group of 5-Fluorouridine and its Application to the Synthesis of 5'-O-Acryloyl-5-Fluorouridine
			T. Akiyama, M. Kumegawa, Y. Takesue, H. Nishimoto, and S. Ozaki, Chem. Lett., 1990, 339-342.
8			5-Fluorouracil Derivatives. XVII. Synthesis and Antitumor Activity of 5'-O -Acyl-5-fluorouridines
			S. Ozaki, T. Akiyama, Y. Ike, H. Mori, and A. Hoshi, Chem. Pharm. Bull., 37, 3405-3408 (1989).
7			Preparation of Potentially Antitumor-Active Vinyl Polymers Having 5-Fluorouracil as a Component
			S. Ozaki, J. Ohnishi, Y. Watanabe, T. Nohda, T. Nagase, T. Akiyama, N. Uehara, and A. Hoshi, Polym. J., 21, 955-958 (1989).
6			Highly Stereoselective Reactions of Carbanions of Dithiabicyclo[3.1.0]hexane Derivatives,
			R. Okazaki, M. O-oka, T. Akiyama, N. Inamoto, J. Niwa, and S. Kato, J. Am. Chem. Soc., 109, 5413-5419 (1987).
5			A Convenient Method for the Synthesis of a-Phenylthio-a,b-Unsaturated Ketone by Stannous Triflate Promoted Rearrangement of a-Sulfinyl Ketone
			T. Akiyama, H. Iwakiri, M. Shimizu, and T. Mukaiyama, Chem. Lett., 1984, 1843-1846.
4			Stannous(II) Triflate Promoted Rearrangement of b-Keto Sulfoxides. Synthesis of 1,4-Diketones
			M. Shimizu, T. Akiyama, and T. Mukaiyama, Chem.Lett., 1984, 1531-1534.
3			Preparation of Chiral Sulfones by Asymmetric Addition of Arenesulfonyl Carbanion to Acetone
			T. Akiyama, M. Shimizu, and T. Mukaiyama, Chem.Lett., 1984, 611-614.
2			Stereospecific Alkylation of Sulfur-Stabilized Carbanion in Dithiabicyclo[3.1.0]hexane Systems
			R. Okazaki, M. O-oka, T. Akiyama, and N. Inamoto, Heterocycles, 18, 241-244 (1982).
1			Bond Switch with Participation of p-Bonded SIV from Isothiazole to Thiadiazole Ring System
			K. Akiba, A. Noda, K. Ohkata, T. Akiyama, Y. Murata, and Y. Yamamoto, Heterocycles, 15, 1155-1158 (1981).