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2026    2025    2024    2023    2022

Publications_2026

1. Fluoride-Coupled Electron Transfer and Hydrogen-Atom-Transfer-Mediated Synthesis of Difluoromethylarenes, Uchikura, T.; Ohashi, K.; Akutsu, F.; Akiyama, T.
Eur. J. Org. Chem. Early View, e202501034.

Publications_2025

1. Transfer Hydrogenation of β-Trifluoromethyl Nitroalkenes Catalyzed by Chiral Calcium Phosphate, Uchikura, T.; Kaneko, Y.; Setogawa, T.; Akiyama, T.
ACS Org. Inorg. Au. 2025, 5, 265−268.
Highlighted in Synfacts, 2025, 21, 937.
2. Electron Donor-Acceptor (EDA) Complex Mediated Visible-Light Driven Sulfur–Fluorine Bond Reduction of Pentafluorosulfanyl Arenes Using Potassium Iodide, Uchikura, T.; Akutsu, F.; Akiyama, T.
Chem. Commun. 2025, 61, 6328-6331.

3. Visible-Light-Driven Racemization of 1,1’-Binaphthyl-2,2’-diamine (BINAM) Derivatives, Uchikura, T.; Sato, M.; Kanno, Y.; Fukuda, Y.; Hara, Y.; Yamamoto, K.; Akiyama, T.
Org. Lett. 2025, 27, 1912−1917.

4. Synthesis of Indole-Fused Benzodiazepine Derivatives by Photocatalyzed Cascade Reaction, Oishi, T.; Uchikura, T.; Akiyama, T.
Chem. Commun. 2025, 61, 2576-2579.

Publications_2024

1. Recent Advances in Catalytic Asymmetric Synthesis, Ojima, I;, Garg, A.: Rendina, D.; Bendale, H.; Akiyama, T.
Front. Chem. 2024, 12, 1398397.

2. Photoreduction of Trifluoromethyl Group: Lithium Ion Assisted Fluoride-Coupled Electron Transfer from EDA complex, Uchikura, T.; Akutsu, F.; Tani, H, Akiyama, T.
Chem. Eur. J. 2024, 30, e202400658.

3. Kinetic resolution of 1,1’-binaphthyl-2,2’-diamine derivatives by chiral calcium phosphate-catalyzed acylation, Uchikura, T.; Kanno, Y.; Fukuda, Y.; Sato, M.; Akiyama, T.
Org. Bioorg. Chem. 2024, 22, 3444-3447.

4. Enantioselective synthesis of 3-(N-indolyl)quinolines containing axial and central chiralities Yamanomoto, K.; Yamamoto, K.; Yoshida, S.; Sato, S.; Akiyama, T.
Chem. Commun. 2024, 60, 582-585.

Publications_2023

1. Visible-light driven enantioselective intermolecular [2+2] photocyclization via bathochromic excitation by chiral phosphoric acid, Uchikura, T.; Takahashi, K.; Oishi, T.; Akiyama, T.
Org. Biomol. Chem. 2023, 21, 9138-9142.

2. Chiral Phosphoric Acid-Palladium(II) Complex Catalyzed Asymmetric Desymmetrization of Biaryl Compounds by C(sp3)–H Activation, Uchikura, T.; Kato, S.; Makino, Y.; Fujikawa, J. M.; Akiyama, T.
J. Am. Chem. Soc. 2023, 145, 15906-15911.

3. 2-Silylated Dihydroquinazolinone as Photocatalytic Energy Transfer Enabled Radical Hydrosilylation Reagent, Uchikura, T.; Nakamura, H.; Sakai, H.; Akiyama, T.
Chem. Eur. J. 2023, 29, e202301090.

4. Enantioselective Synthesis of All-Carbon Quaternary Stereocenter by Chiral Brønsted Acid Catalyzed Friedel–Crafts Type Reaction between Pyrroles and 3-Indolylmethanols, Uchikura, T.; Sánchez-Sordo, I.; Yoshimura, T.; Makino, Y.; Osakabe, H.; Akiyama, T.
J. Org. Chem. 2023, 88, 7774–7783.

5. Metal–and Additive–Free Synthesis of α-Hydroxyamino Ketones Enabled by Organophotocatalyst, Yamanomoto, K.; Matsudaira, T.; Akiyama, T.
Synlett 2023, 34, 1391-1394.

Publications_2022

1. Dual-Role Halogen-Bonding-Assisted EDA-SET/HAT Photoreaction System with Phenol Catalyst and Aryl Iodide: Visible-Light-Driven Carbon–Carbon Bond Formation, Uchikura, T.; Tsubono, K.; Hara, Y.; Akiyama, T.
J. Org. Chem. 2022, 87, 15499-15510.

2. Enantioselective Friedel–Crafts Alkylation Reaction of Pyrroles with N-Unprotected Alkynyl Trifluoromethyl Ketimines, Uchikura, T.; Aruga, K.; Suzuki, R.; Akiyama, T.
Org. Lett. 2022, 24, 4699-4703.

3. Visible-Light Driven Enantioselective Radical Addition to Imines Enabled by Excitation of Chiral Phosphoric Acid–Imine Complex, Uchikura, T.; Kamiyama, N.; Mouri, T.; Akiyama, T.
ACS Catal. 2022, 12, 5209–5216.

4. Chiral Calcium Phosphate Catalyzed Enantioselective Synthesis of All-Carbon Quaternary Center by Friedel–Crafts Alkylation Reaction of Pyrroles and Trifluoromethylated Nitrostyrenes, Uchikura, T.; Yokohama, S.; Murakami, M.; Akiyama, T.
Synthesis 2022, 54, 3793-3800.

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